| THE PHOTOCHEMICAL SYNTHESIS OF THE PYRIDINE ADDUCT OF TETRAPHENYLPORPHYRINATORHODIUM(Ⅱ)AND THE MECHANISM OF PHOTOCHEMICAL REACTION |
| |
| 作者姓名： | A.K.Hsieh |
| |
| 作者单位： | 1.Department of Chemistry, Department of Physics# , Zhongshan University, Guangzhou 510275;2.Department of Chemistry, National University of Singapor |
| |
| 基金项目： | Project Supported by Science Research Foundation of Zhongshan University, National Natural Science Foundation of P. R. C^na and Resarch Fund of Royai Society of Chemistry |
| |
| 摘 要： | A new rhodium(Ⅱ)porphyrin complex was isolated by chromatography from the photochemical reac-tion of(μ—tetraphenylporphyrinato)bisdicarbonylrhodium(Ⅰ)]with pyridine in benzene and has been charac-terized.From the results,the reaction mechanism is proposed.
|
THE PHOTOCHEMICAL SYNTHESIS OF THE PYRIDINE ADDUCT OF TETRAPHENYLPORPHYRINATORHODIUM(Ⅱ) AND THE MECHANISM OF PHOTOCHEMICAL REACTION |
| |
| A.K.Hsieh.THE PHOTOCHEMICAL SYNTHESIS OF THE PYRIDINE ADDUCT OF TETRAPHENYLPORPHYRINATORHODIUM(Ⅱ) AND THE MECHANISM OF PHOTOCHEMICAL REACTION[J].Chinese Chemical Letters,1991,2(4):279-280. |
| |
| Authors: | Jin Wang HUANG Liang Nian JI Yu Dong SU He Zhcu WANG A K Hsieh |
| |
| Institution: | 1.Department of Chemistry, Department of Physics# , Zhongshan University, Guangzhou 510275;2.Department of Chemistry, National University of Singapor |
| |
| Abstract: | A new rhodium(Ⅱ) porphyrin complex was isolated by chromatography from the photochemical reaction of(μ—tetraphenylporphyrinato)bisdicarbonylrhodium(Ⅰ)]with pyridine in benzene and has been characterized.From the results,the reaction mechanism is proposed. |
| |
| Keywords: | |
| 本文献已被 CNKI 等数据库收录！ |
| 点击此处可从《中国化学快报》浏览原始摘要信息 |
| 点击此处可从《中国化学快报》下载免费的PDF全文 |
