Chlorokomplexe von 3 d5-Ionen in nichtwäßrigen Lösungen |
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| Authors: | V. Gutmann W. Lux |
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| Affiliation: | 1. Institut für Anorganische Chemie der Technischen Hochschule Wien, Wien, ?sterreich
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| Abstract: | The chloro systems of Mn2+ and Fe3+ were investigated in acetonitrile (AN), propanediole-1,2-carbonate (PDC) and trimethylphosphate (TMP) by spectrophotometric, potentiometric and conductometric methods. The following coordination forms seem to be present: MnCl2 (inAN, PDC andTMP), [MnCl4]2? (tetrahedral inAN, octahedral inTMP), [MnCl6]4? (octahedral inPDC andTMP); [FeCl]2+ (tetrahedral inAN andPDC), [FeCl2]+ (tetrahedral inTMP), FeCl3 (tetrahedral inAN andPDC), [FeCl4]? (tetrahedral inAN, PDC andTMP). |
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