Azidokomplexe in nichtwäßrigen Lösungsmitteln, 3. Mitt.: Ti(III), V(III) und Cr(III) in Acetonitril,Propandiol-1,2-carbonat und Trimethylphosphat |
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| Authors: | V Gutmann O Leitmann A Scherhaufer H Czuba |
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| Institution: | 1. Institut für Anorganische Chemie der Technischen Hochschule Wien, Wien, ?sterreich
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| Abstract: | Ions of Ti(III), V(III) and Cr(III) seem to be converted to the following azido complexes in acetonitrile, propanediol-1,2-carbonate and trimethylphosphate: Ti(N3)2]+ (inTMP), Ti(N3)3 (probably distorted octahedral inAN, PDC andTMP, low solubility inTMP), Ti(N3)4]? (probably tetragonal inAN, probably octahedral inTMP), Ti(N3)6 3? (probably distorted octahedral inAN andPDC); V(N3)]2+ (inAN, PDC andTMP), V(N3)3 (octahedral inAN, PDC andTMP, low solubility inTMP), V(N3)4]? (inPDC), V(N3)6]3? (octahedral inAN andPDC); Cr(N3)]2+ (inTMP), Cr(N3)2]+ (octahedral inAN andPDC), Cr(N3)3 (octahedral inAN, PDC andTMP), Cr(N3)6]3? (octahedral inAN andPDC). |
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