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Hetero‐Epitaxial Approach by Using Labile Coordination Sites to Prepare Catenated Metal–Organic Frameworks with High Surface Areas |
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| Authors: | Dr Nianyong Zhu Matthew J Lennox Gerard Tobin Lisa Goodman Dr Tina Düren Prof Wolfgang Schmitt |
| Institution: | 1. School of Chemistry & CRANN, University of Dublin, Trinity College, Dublin 2 (Ireland);2. Institute for Materials and Processes, School of Engineering, The University of Edinburgh, The King's Buildings, Edinburgh, EH9 3JL (UK) |
| Abstract: | A solid‐state approach that takes advantage of the ordered 3D arrangement of active secondary building units allows the preparation of new interlocked MOFs that grow hetero‐epitaxially on the crystal faces of a precursor phase that acts as a “topological blueprint”. The synthetic strategy is exemplified by using rigid acetylene‐based ligands to produce highly augmented CuII acetate‐based MOFs. |
| Keywords: | coordination chemistry copper epitaxy metal– organic frameworks supramolecular chemistry |