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Combining Complementary Ligands into one Framework for the Construction of a Ferromagnetically Coupled [MnIII12] Wheel |
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| Authors: | Dr. Sergio Sanz Jamie M. Frost Thayalan Rajeshkumar Dr. Scott J. Dalgarno Dr. Gopalan Rajaraman Dr. Wolfgang Wernsdorfer Prof. Jürgen Schnack Dr. Paul. J. Lusby Prof. Euan K. Brechin |
| Affiliation: | 1. EaStCHEM School of Chemistry, The University of Edinburgh, West Mains Road, Edinburgh, EH9 3JJ (UK);2. Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai 400 076 (India);3. Institute of Chemical Sciences, Heriot‐Watt University, Riccarton, Edinburgh, Scotland, EH14 4AS (UK);4. Institut Néel, 25 Avenue des Martyrs, BP 166, 38042 Grenoble, Cedex 9 (France);5. Universit?t Bielefeld, Fakult?t für Physik, Postfach 100131, 33501 Bielefeld (Germany) |
| Abstract: | Phenolic oxime and diethanolamine moieties have been combined into one organic framework, resulting in the formation of a novel ligand type that can be employed to construct a rare and unusual dodecametallic Mn wheel, within which nearest neighbours are coupled ferromagnetically. |
| Keywords: | density functional calculations finite‐temperature Lanczos method manganese molecular magnets self‐assembly |