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Novel Quasi-solid-state Dye-sensitized Solar Cell Based on Monolayer Capped TiO2 Nanoparticles Framework Materials
作者姓名:夏江滨  李富友  黄春辉
作者单位:[1]StateKeyLaboratoryofRareEarthMaterialChemistryandApplications,PekingUniversity,Beijing100871,China [2]InstituteofAdvancedMaterial,FudanUniversity,Shanghai200433,China
基金项目:Project supported by the State Key Program of Fundamental Research (No. G1998061308),the National High Technology Research Development Plan of China (Nos. 2002 AA 302403 and 0216nm040) and the National Natural Science Foundation of China (No. 20221101)
摘    要:Dodecylbenzenesulfonate (DBS)-capped TiO2 nanoparticles have been synthesized and employed in dye-sensitized solar cells to form a quasi-solid state electrolyte. Owing to the long alkyl-chain capping around the TiO2 nanoparticles interacting with the liquid solvent, the dye sensitized solar cell based on such DBS-capped TiO2 nanoparticle framework material gel electrolyte shows higher stability compared with the non-capped one in the long-term application and gives a comparable overall efficiency of 6.3% at AM 1.5 illumination.

关 键 词:染料激活太阳能电池  二氧化钛纳米粒子  类固态  十二烷基苯磺酸盐  单层覆盖

Novel Quasi-solid-state Dye-sensitized Solar Cell Based on Monolayer Capped TiO_2 Nanoparticles Framework Materials
XIA,Jiang-Bina LI,Fu-You,b HUANG,Chun-Hui,a,b a State Key Laboratory of Rare Earth Material Chemistry and Applications,Peking University,Beijing ,China b Institute of Advanced Material,Fudan University,Shanghai ,China.Novel Quasi-solid-state Dye-sensitized Solar Cell Based on Monolayer Capped TiO2 Nanoparticles Framework Materials[J].Chinese Journal of Chemistry,2004,22(7):687-690.
Authors:XIA  Jiang-Bina LI  Fu-You  b HUANG  Chun-Hui  a  b a State Key Laboratory of Rare Earth Material Chemistry and Applications  Peking University  Beijing  China b Institute of Advanced Material  Fudan University  Shanghai  China
Institution:XIA,Jiang-Bina LI,Fu-You*,b HUANG,Chun-Hui*,a,b a State Key Laboratory of Rare Earth Material Chemistry and Applications,Peking University,Beijing 100871,China b Institute of Advanced Material,Fudan University,Shanghai 200433,China
Abstract:Dodecylbenzenesulfonate (DBS)-capped TiO2 nanoparticles have been synthesized and employed in dye-sensitized solar cells to form a quasi-solid state electrolyte. Owing to the long alkyl-chain capping around the TiO2 nanoparticles interacting with the liquid solvent, the dye sensitized solar cell based on such DBS-capped TiO2 nanoparticle framework material gel electrolyte shows higher stability compared with the non-capped one in the long-term application and gives a comparable overall efficiency of 6.3% at AM 1.5 illumination.
Keywords:dodenylbenzenesufonate  capped TiO2  dye-sensitized solar cells  quasi-solid state
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