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ZnCl2-catalyzed hydrodefluorination of gem-difluoromethylene derivatives with lithium aluminum hydride |
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| Authors: | Jianhang ChengJingjing Wu Song Cao |
| Institution: | Shanghai Key Laboratory of Chemical Biology, School of Pharmacy, East China University of Science and Technology, Shanghai 200237, China |
| Abstract: | Hydrodefluorination of gem-difluoromethylene derivatives with lithium aluminum hydride in the presence of a catalytic amount of ZnCl2 in good to high yields was described. A possible mechanism is also suggested. |
| Keywords: | Hydrodefluorination gem-Difluoromethylene derivatives Lithium aluminum hydride Zinc chloride Catalyst |
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