A combined experimental and theoretical study on the complexation of the ammonium ion with benzo-18-crown-6 |
| |
| Authors: | Petr Toman Emanuel Makrlík and Petr Vaňura |
| |
| Institution: | (1) Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Prague, Czech Republic;(2) Faculty of Applied Sciences, University of West Bohemia, Pilsen, Czech Republic;(3) Institute of Chemical Technology, Prague, Czech Republic; |
| |
| Abstract: | Abstract From extraction experiments in the two-phase water/nitrobenzene system and γ-activity measurements, the stability constant of the benzo-18-crown-6–ammonium complex in nitrobenzene saturated with water
was determined. Furthermore, the structure of the resulting complex was derived by means of theoretical calculations at the
density functional level. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
