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Scope, limitations and mechanistic aspects in the selective homogeneous palladium-catalyzed reduction of alkenes under transfer hydrogen conditions |
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| Authors: | Jean Michel Brunel |
| Institution: | Laboratoire Synthèse et Etude de Substances Naturelles à Activités Biologiques (SESNAB), Faculté des Sciences et Techniques de St Jéroˆme, Case 342, Université Paul Cézanne, Aix-Marseille III, Avenue Escadrille Normandie Niémen, 13397 Marseille Cedex 20, France |
| Abstract: | A new and efficient mild Pd/P(t-Bu)3 catalyst for selective reduction of various alkenes under transfer hydrogen conditions has been developed leading to the corresponding saturated derivatives in chemical yields varying from 65 to 98%. Mechanistic rationale of this reaction has been also demonstrated. |
| Keywords: | Palladium Reduction of alkenes Tri-tert-butyl phosphine Transfer hydrogen Catalysis |
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