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BF3-OEt2-mediated rearrangement of 4-substituted-5,5-diphenylazepan-4-ols
Authors:Meng-Yang Chang  Yung-Hua Kung  Tsun-Cheng Wu
Affiliation:Department of Applied Chemistry, National University of Kaohsiung, Kaohsiung 811, Taiwan
Abstract:Synthesis of 2-(2-substituted-ethylidene)-3,3-diphenylpyrrolidines has been established starting from different 4-substituted-4-aryl-5,5-diphenylazepan-4-ols via boron trifluoride etherate-mediated rearrangement.
Keywords:m-Chloroperoxybenzoic acid   Boron trifluoride etherate   Grignard reagent   5,5-Diphenylazepan-4-one   3,3-Diphenylpyrrolidine
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