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Sparsely substituted chlorins as core constructs in chlorophyll analogue chemistry. II. Derivatization
Authors:Taniguchi Masahiko  Ptaszek Marcin  McDowell Brian E  Lindsey Jonathan S
Institution:Department of Chemistry, North Carolina State University, Raleigh, NC 27695-8204, USA
Abstract:Stable chlorins bearing few or no substituents have been subjected to a variety of reactions including demetalation, magnesium insertion, oxochlorin formation, and bromination followed by Suzuki coupling. The kinetics of deuteration also have been determined for two oxochlorins and a series of chlorins bearing 0, 1, 2, or 3 meso-aryl substituents.
Keywords:Chlorin  Deuteration  Bromination  Metalation
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