Sparsely substituted chlorins as core constructs in chlorophyll analogue chemistry. I. Synthesis |
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| Authors: | Ptaszek Marcin McDowell Brian E Taniguchi Masahiko Kim Han-Je Lindsey Jonathan S |
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| Affiliation: | Department of Chemistry, North Carolina State University, Raleigh, NC 27695-8204, USA |
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| Abstract: | Five routes to stable chlorins bearing 0 or 1 meso substituents have been investigated, among which reaction of a 9-bromo-1-formyldipyrromethane and 2,3,4,5-tetrahydro-1,3,3-trimethyldipyrrin proved most effective. Application of this route afforded metallochlorins [Cu(II), Zn(II), and Pd(II)] including the chlorin lacking any β-pyrrole and meso substituents. |
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| Keywords: | Chlorin Hydroporphyrin Hydrodipyrrin Dipyrromethane |
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