Abstract: | By reaction of pentafluorophenylhydrazine with metal chlorides the complexes M(NH2NHC6F5)4Cl2 (M = Co, Ni), M(NH2NHC6F5)2Cl2 (M = Mn, Fe, Pd, Zn, Cd), Cu(NH2NHC6F5)Cl, and Hg(NH2NHC6F5)2Cl were obtained. From Cr(CO)6 and pentafluorophenylhydrazine the complex Cr(CO)5(NH2NHC6F5) was synthesized. |