Kinetics and Mechanism of Electron Transfer Reactions: Oxidation of Crotyl Alcohol by Peroxomonosulfate in Aqueous Acidic Medium |
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Abstract: | The kinetics and mechanism of oxidation of crotyl alcohol by peroxomonosulfate has been studied, and the species of the peroxomonosulfate are discussed to find out the role of activated species. A plausible reaction mechanism is suggested, and a derived rate law corresponds to all experimental observations. The activation parameters such as energy and entropy of activation have been calculated as 37.21 ± 0.5 kJ mol−1 and −148.91 ± 2.7 J K−1 mol−1, respectively, by employing the Eyring plot. |
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