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Synthesis and X‐ray Crystal Structures of Homotrimetallic Zinc Bisureate Complexes |
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| Abstract: | Alkane elimination reactions of the tethered bis(urea) proligand 1,4‐(tBuNHCONH)2‐C4H8 ( 1 ) with ZnR2 (R = Me, Et, nPr) yielded trimetallic zinc complexes [RZn‐1,4‐(tBuNHCON)2‐C4H8]2Zn [R = Me ( 2 ), Et ( 3 ), and nPr ( 4 )]. 2 – 4 were characterized by heteronuclear NMR (1H, 13C) and IR spectroscopy, elemental analysis, and single‐crystal X‐ray diffraction. |
| Keywords: | Bis(ureate) Zinc Single crystal |