| 基于MX_4结构的配位化合物析氢反应催化性能 |
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| 引用本文： | 姚会影,杨涛,黄幸,朱嘉,李青,徐伟,迟力峰.基于MX_4结构的配位化合物析氢反应催化性能[J].应用化学,2018,35(3):328-341. |
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| 作者姓名： | 姚会影 杨涛 黄幸 朱嘉 李青 徐伟 迟力峰 |
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| 作者单位： | 北京师范大学化学学院 理论与光化学教育部重点实验室 北京 100875;苏州大学功能纳米与软物质研究院 江苏 苏州 215123;中国科学院化学研究所 有机固体实验室 北京 100190 |
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| 基金项目： | 国家自然基金(21773016)资助 |
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| 摘 要： | 具有MX4结构的(M=Fe,Co,Ni,Cu等,X=N,S,Se等)小分子配位化合物及配位聚合物(MX4催化剂),由于其新颖的结构和优异的电催化析氢性能受到研究人员越来越多的关注。本文综述了MX4催化剂的研究进展,其中MX4催化剂活性受金属中心、配位原子、配体的结构以及材料的形貌、尺寸等因素的影响。理论计算有助于分析催化剂中这些因素对催化剂活性的影响,也有助于通过理论模拟,设计更合理的催化剂分子结构。
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| 关 键 词： | 催化析氢反应 配位化合物 MX4结构 |
| 收稿时间： | 2017-12-14 |
Coordination Complexes Based on MX4 Structure as Catalyst for Hydrogen Evolution Reaction |
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| YAO Huiying,YANG Tao,HUANG Xing,ZHU Jia,LI Qing,XU Wei,CHI Lifeng.Coordination Complexes Based on MX4 Structure as Catalyst for Hydrogen Evolution Reaction[J].Chinese Journal of Applied Chemistry,2018,35(3):328-341. |
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| Authors: | YAO Huiying YANG Tao HUANG Xing ZHU Jia LI Qing XU Wei CHI Lifeng |
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| Institution: | Key Laboratory of Theoretical and Computational Photochemistry of Ministry of Education,College of Chemistry,Beijing Normal University,Beijing 100875,China;Institute of Functional Nano & Soft Materials,Soochow University,Suzhou,Jiangsu 215123,China;Beijing National Laboratory for Molecular Sciences CAS Key Laboratory of Organic Solids,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100190,China |
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| Abstract: | The coordination complexes based on MX4(M=Fe,Co,Ni,Cu, et al, X=N,S,Se, et al.) structure have attracted a lot of attentions due to their novel structure and good electrocatalytic performance in hydrogen evolution reaction(HER). This review shows the recent research progresses of their catalytic properties for HER. The HER activities of MX4 catalysts are affected by many factors, such as the metal center, coordination atoms, the ligand, the morphology and size of catalysts. Theoretical calculations are very helpful for understanding their influences on the activities of the catalysts and can further help us design more catalysts with higher activities. |
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| Keywords: | catalytic hydrogen evolution reaction coordination complex MX4 structure |
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