Syntheses based on 2-ethoxycarbonylmethyl-7-methyl-1,3,4-thiadiazolo[3,2-a]pyrimidin-5(5H)-one |
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Authors: | M. A. Kukaniev S. Sh. Shukurov Yu. Khodzhibaev N. Kurbonova S. G. Bandaev |
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Affiliation: | (1) V. I. Nikitin Institute of Chemistry, Academy of Sciences of Republic Tajikistan, 299 ul. Aini, 734069 Dushanbe, Tajikistan |
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Abstract: | 2-Ethoxycarbonylmethyl-7-methyl-1,3,4-thiadiazolo[3,2-a]pyrimidin-5(5H)-one containing the active methylene group reacts easily with carbon disulfide and phenyl isothiocyanate in the presence of sodium hydride. Further alkylation of the reaction product by alkyl halides results in the formation of the corresponding 1,3,4-thiadiazolo[3,2-a]pyrimidine derivatives containing a ketene dithioacetal fragment. Deceased. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2371–2373, November, 1998. |
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Keywords: | 2-ethoxycarbonylmethyl-7-methyl-1,3,4-thiadiazolo[3,2-a]pyrimidin-5(5H)-one 1,3,4-thiadiazolo[3,2-a]pyrimidines ethyl (7-methyl-5-oxo-5H-1,3,4-thiadiazolo-[3,2-a]pyrimidin-2-yl)methylthiothiocarbonylacetate ethyl 2-(7-methyl-5-oxo-5H-1,3,4-thiadiazolo[3,2-a]pyrimidin-2-yl)-3,3-bis(methylthio)acrylate |
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