We synthesized 102 new 1,4-bis-[4-subst.-benzoyloxy]-2-n-alkylbenzenes of the general formula with R = alkyl, alkyloxy, alkanoyloxy, alkyloxycarbonyloxy and n = 0 to 16. Surprisingly all of the new compounds are liquid crystalline nematic. Thus it is proved that lateral long chain substituents are compatible with liquid crystalline properties.