The Nasicon-like copper(II) zirconium phosphate Cu0.5Zr2(PO4)3 and related compounds |
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| Institution: | 1. School of Environmental and Chemical Engineering, Shanghai University, No. 333 Nanchen Rd., Shanghai 200444, PR China;2. School of Chemistry, Physics and Mechanical Engineering, Science and Engineering Faculty, Queensland University of Technology, GPO Box 2434, Brisbane QLD 4001, Australia |
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| Abstract: | A new family of Nasicon-like zirconium phosphates of formula M0.5Zr2(PO4)3 with M = Ca, Cu, Sr, Cd or Pb has been described. The physical properties of the copper compound have been investigated in detail in which Cu2+ induces a Jahn-Teller distortion below 520°C. Crystal field, electron paramagnetic resonance, and magnetic data are consistent with an elongated octahedral surrounding of the Cu2+ ions. |
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