Magnetic properties of ammonia intercalates of some IV B and V B transition metal disulfides期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Magnetic properties of ammonia intercalates of some IV B and V B transition metal disulfides

Affiliation:	1. Thin Film Device Fabrication & Characterisation Laboratory, Department of Physics, Sardar Patel University, Vallabh Vidyanagar 388120, Gujarat, India;2. Department of Physical Sciences, P. D. Patel Institute of Applied Science, CHARUSAT Campus, Highway 139, Off. Nadiad-Petlad Road, Changa-388421, Gujarat, India;3. Department of Physics, The M. S. University of Baroda, Pratapgunj, Vadodara-390002, Gujarat, India;4. Sophisticated Instrumentation Centre for Applied Research and Testing (SICART), Vallabh Vidyanagar-388 120, Anand, Gujarat, India;5. Material Design Division, Faculty of Materials Science and Engineering, Warsaw University of Technology, 141 Woloska Str., 02‑507 Warsaw, Poland;1. Division of Biomedical Engineering, School of Engineering, University of Glasgow, Glasgow, G128LT, UK;2. Structured Photonics Group, School of Engineering, University of Glasgow, Glasgow, G128LT, UK

Abstract:	Intercalates 3RVS₂NH₃ and 3RTaS₂NH₃, isostructural with 3RTiS₂NH₃, are described for the first time. Magnetic properties of 3RTiS₂NH₃, 3RVS₂NH₃, and 2HTaS₂NH₃ respectively are interpreted in terms of a charge transfer (in agreement with an ionic model) from the intercalant to the lowest conduction band which consists mainly ofe_g, a_1g anda′₁ transition metald states.

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