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Millimeter and sub-millimeter wave detection of hydrogen peroxide
Institution:1. Univ. Grenoble Alpes, CNRS, LIPhy, Grenoble, France;2. Institute of Applied Physics of RAS, Nizhniy Novgorod, Russia;3. Laboratory of Theoretical Spectroscopy, V.E. Zuev Institute of Atmospheric Optics, SB, Russian Academy of Science, 1, Academician Zuev square, 634055 Tomsk, Russia;4. Climate and Environmental Physics Laboratory, Ural Federal University, 19, Mira av., 620002 Yekaterinburg, Russia
Abstract:The measurement of small concentrations of hydrogen peroxide through the detection of rotational transitions in the millimeter and sub-millimeter wave regions is discussed. Calculated transition frequencies and absorption coefficients of H2O2 for frequencies up to 2000 GHz are presented. The reliability of the calculated values is illustrated by measurements of the linewidths and absorption coefficients of transitions in the 140 GHz range. Finally, methods for the detection of trace quantities of the peroxide molecule are briefly described.
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