Double End‐On Azido Copper(II) Dinuclear Complex with Oxazoline Ligand: Synthesis,Structure, Magnetic Properties and Theoretical Study |
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Authors: | Min Cheng Dongmei Lu En‐Qing Gao Qin‐Xiang Jia |
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Affiliation: | 1. Department of Chemistry, School of Science, Xi'an Jiaotong University, Xi′an, Shaan Xi, 710049, P. R. China;2. Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, P. R. China |
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Abstract: | A double azido‐bridged CuII dinuclear complex with the chelating chiral ligand, [Cu2(L)2(N3)4] ( 1 ) [L = (+)‐2, 2′‐isopropylidene‐bis((4R)‐4‐benzyl‐2‐oxazoline)] was synthesized and characterized by single‐crystal X‐ray diffraction, IR spectroscopy, magnetic measurements, and theoretical studies. The asymmetric double end‐on azido bridges in complex 1 lead to a weak antiferromagnetic behavior with J = –7.4 cm–1. The exchange interactions in complex 1 were investigated by DFT calculations, and the calculated exchange interaction (J = –8.0 cm–1) is in good agreement with the experimental value. |
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Keywords: | Azides Copper Dinuclear Magnetic properties Theoretical Study |
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