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Synthesis and Characterization of Bis(2‐iminopyrrolyl) Iron(II) Complexes by N–H Bond Activation |
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| Authors: | Guili Jiao Gengyu Zhu Shumiao Zhang Hongjian Sun |
| Institution: | 1. School of Chemistry and Chemical Engineering, Key Laboratory of Special Functional Aggregated Materials, Ministry of Education, Shandong University, Shanda Nanlu 27, 250199 Jinan, P. R. China;2. Hydrology Bureau of Shandong Province, Shunshi Road 1, 250002 Jinan, P. R. China |
| Abstract: | The reactions of 2‐iminopyrroles 1 – 3 with Fe(PMe3)4 afforded the N–H activated bis(2‐iminopyrrolyl) iron(II) complexes 4 – 6 . The structures of compounds 4 – 6 were determined by single‐crystal X‐ray diffraction. The formation mechanism of complexes 4 – 6 was discussed. |
| Keywords: | 2‐Iminopyrrole Iron N– H activation Trimethylphosphine |