Solvent‐Dependent Synthesis from Layer to Microporous Pillared‐Layer Framework for Selective Sorption of Gas Light Hydrocarbons |
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| Authors: | Zhiqiang Jiang Yun An Xuejun Zhu Congxue Tian Jing Bai Yufeng Li |
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| Institution: | 1. Panzhihua Key Laboratory of Chemical Resource Engineering, Panzhizua University, Panzhihua 617000, P. R. China;2. State Key Laboratory for Vanadium & Titanium Testing (Preparatory), Panzhizua University, Panzhihua 617000, P. R. China |
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| Abstract: | Three metal‐organic frameworks, Zn3(bdc)3(DMA)2] ( 1 ) (H2bdc = terephthalic acid; DMA = N,N‐dimethylacetamide), Zn3(bdc)3(DMA)(DMPU)] ( 2 ) (DMPU = 1,3‐dimethylpropyleneurea), and Zn3(bdc)4(Hdma)2] ( 3 ) Hdma = protonated dimethylamine (Me2NH2)] were synthesized by using different solvents. The solvents determine the framework architectures range from layer to microporous pillared‐layer framework. The microporous framework has 8‐connected bcg topology and shows selective sorption ability for gas light hydrocarbons. |
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| Keywords: | Metal‐organic frameworks Solvent‐dependent synthesis Zinc Selective sorption Hydrocarbons |
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