Synthesis,Structures and Magnetic Properties of Cyano‐bridged FeIII/MnIII Heterobimetallic 1D Chain Complexes |
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| Authors: | Feng Gao Guang‐Zhou Zhu Liu Yang |
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| Affiliation: | School of Chemistry and Chemical Engineering, Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials, Jiangsu Normal University, Xuzhou 221116, P. R. China |
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| Abstract: | Using the tricyanometalate building block, (nBu4N)[(Tp*)Fe(CN)3] [Bu4N+ = tetrabutylammonium cation; Tp*– = hydrotris(3,5‐dimethylpyrazol‐1‐yl)borate], and bidentate Schiff base ligands, HL1 or HL2 {HL1 = 2‐[[(2‐phenylethyl)imino]methyl]phenol; HL2 = 4‐methoxy‐2‐[[(2‐phenylethyl)imino]methyl]phenol}, two heterobimetallic one‐dimensional (1D) chain complexes, [Mn(L1)2Fe(Tp*)(CN)3]n ( 1 ) and [Mn(L2)2Fe(Tp*)(CN)3]n ( 2 ), were synthesized. Single crystal X‐ray diffraction reveal the formation of neutral cyano‐bridged zigzag single chains in 1 and 2 . Magnetic studies demonstrate that both complexes show ferromagnetic interactions between central FeIII and MnIII atoms. |
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| Keywords: | Tricyanometalate Magnetic properties 1D chain Manganese |
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