反气相色谱法研究结晶聚合物的结晶行为

 :采用反气相色谱法(IGC)测定了结晶聚合物聚乙二醇(PEG)的熔点和结晶度,探讨了探针分子的性质、固定相中聚合物的涂布量对测定结果的影响,同时与热分析(DSC)方法测得的结果作了比较。结果表明,IGC法测定结晶性聚合物熔点和结晶度是一种非常实用可靠的技术,其优点在于并不依赖100%纯结晶聚合物的性质,PEG的熔点测得值为67℃,结晶度为89.7%,测定结果与DSC法的测得值(Tm=67.9℃,Xc=90.6%)相近,所测定的结果与探针分子的性质无关,但受PEG在担体上的涂布量的影响显著。

Study of the Crystalline Behaviors of Polymer by Inverse Gas Chromatography

An investigation was made on crystallinity(Xc) and melting temperature(Tm) of the crystalline polymer polyethylene glycol(PEG) by inverse gas chromatography(IGC). The influence of the property of the probe and the coating weight of PEG in stationary phase on the data determined is discussed. And IGC data are compared with those got by differential scanning calorimetric (DSC) experiment. Results showed that IGC is a very useful technique for measuring the melting point and the degree of crystallinity of polymer samples since it does not depend on the assumptions about the properties of 100% crystalline polymer. IGC data indicated that the melting temperature of PEG was 67 degrees C and crystallinity was 89.7%. DSC data indicated the same results. The experimental data was found to be not related with the chemical nature of the probes, but depended on the coating weight of PEG on the supports.