Structural diversity in the assembly of helicate-type nickel(II) complexes with enantiopure bis(beta-diketonate) ligands |
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| Authors: | Albrecht Markus Dehn Sabrina Raabe Gerhard Fröhlich Roland |
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| Affiliation: | Institut für Organische Chemie der RWTH-Aachen, Landoltweg 1, Aachen, 52074, Germany. markus.albrecht@oc.rwth-aachen.de |
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| Abstract: | The tartaric acid derived bis(beta-diketonate) ligand L affords either 2:3 or 3:2 ligand:metal complexes with nickel(II) ions depending on the stoichiometry of the components; the two complexes possess different electronic and geometric properties. |
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