Ionization energies of LinX (n = 2, 3; X = Cl, Br, I) molecules |
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Authors: | Velicković Suzana Djordjević Vesna Cvetićanin Jelena Djustebek Jasmina Veljković Miomir Nesković Olivera |
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Institution: | VINCA Institute of Nuclear Science, P.O. Box 522, 11001 Belgrade, Serbia. vsuzana@vin.bg.ac.yu |
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Abstract: | Molecules of Li(n)X (n = 2, 3; X = Cl, Br, I) were examined with a magnetic sector mass spectrometer by surface ionization using a triple rhenium filament impregnated with fullerene (C60). The ionization energies obtained for Li(2)Cl, Li(2)Br and Li(2)I molecules are 3.8 +/- 0.1, 3.9 +/- 0.1 and 4.0 +/- 0.1 eV, respectively. The first ionization energy of Li(2)Cl is documented, while there are no literature data for the ionization energies of Li(2)Br and Li(2)I. The molecules of Li(3)Cl, Li(3)Br and Li(3)I were detected experimentally for the first time with ionization energies of 4.0 +/- 0.1, 4.1 +/- 0.1 and 4.1 +/- 0.1 eV, respectively. The ionization energies of Li(n)X (n = 2, 3; X = Cl, Br, I) are in correlation with the theoretical prediction of their hyperlithiated configurations. |
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