Radiation induced preparation of new multifunctional nanobiowebs |
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Authors: | Gopalan Anantha Iyengar Kyung Ryeol Ko Se-Hee Lee Komathi Shanmugasundaram Miklos Veres Kwang-Pill Lee |
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Affiliation: | 1. Department of Nano-Science & Technology, Kyungpook National University, Daegu, South Korea;2. Department of Chemistry Graduate School, Kyungpook National University, Daegu, South Korea;3. Research Institute of solid state physics and optics, Budapest, Hungary;1. School of Materials Science and Chemical Engineering, Tianjin University of Science & Technology, Tianjin 300457, PR China;2. College of Science, Tianjin University of Science & Technology, Tianjin 300457, PR China;1. Department of Electronics Engineering, Dong-A University, South Korea;2. Kolon Glotech, INC., South Korea;1. School of Chemistry and Material Science, Jiangsu Provincial Key Laboratory of Materials Cycling and Pollution Control, Nanjing Normal University, Nanjing 210097, China;2. Department of Engineering and Technology, Jiangsu Institute of Commerce, Nanjing 211168, China;3. Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse, Nanjing University of Science and Technology, Nanjing 210094, P.R. China |
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Abstract: | New poly(vinylidene fluoride) based multi-functional (electroconductive, bioactive and catalytic) nano-biowebs were prepared through gamma radiation induced formation of silica and gold nanoparticles (Au NPs) within electrospun (poly vinylidene fluoride) nanofiberous membranes. The multifunctional membrane is designated as PVdF@silica/Au ESNFM. The morphology of PVdF@silica/Au ESNFM was examined by field emission scanning electron microscopy. The presence of Au particles was confirmed by energy dispersive x-ray analysis. The crystal structure of Au particles and the formation of silica were confirmed by X-ray diffraction analysis. The multi-functionalities (electroconductive, bioactive and catalytic) of the nano-webs were evaluated by cyclic voltammetry. Cytochrome c was immobilized to generate nano-bioweb (PVdF@silica/Au/cyt c ESNFM), which exhibited electrochemical responses to nitrite ions. |
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