Synthesis and characterization of radiation grafted films for removal of arsenic and some heavy metals from contaminated water |
| |
| Authors: | M.N.K. Chowdhury M.W. Khan M.F. Mina M.D.H. Beg Maksudur R. Khan A.K.M.M. Alam |
| |
| Affiliation: | 1. Faculty of Engineering, Bangladesh University of Engineering & Technology, Dhaka 1000, Bangladesh;2. Faculty of Chemical & Natural Resources Engineering, Universiti Malaysia Pahang, 26300 Gambang, Kuantan, Malaysia;1. Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima, Japan;2. Research Reactor Institute, Kyoto University, Kumatori, Japan;3. Center of Medical Education, Sapporo Medical University, Sapporo, Japan;1. School of Chemical Engineering, Guizhou Minzu University, Guiyang, 550025, China;2. Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan, 430079, China;1. School of Chemical Engineering, Sichuan University, Chengdu 610065, China;2. School of Food and Bioengineering, Xihua University, Chengdu 610039, China;3. College of Life Science & Biotechnology, Mianyang Normal University, Mianyang 621000, China;1. College of Science, Beijing Forestry University, Beijing 100083, China;2. College of Biological Sciences and Biotechnology, Beijing Forestry University, Beijing 100083, China;3. Beijing Key Laboratory of Forest Food Processing and Safety, Beijing 100083, China;1. Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, Key Laboratory of High Performance Polymer Materials and Technology, The State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, PR China;2. School of Physical Science and Technology, Xinjiang Key Laboratory and Phase Transitions and Microstructures in Condensed Matters, Yili Normal University, Yining 835000, PR China;3. Institute of Physics, University of Rostock, Wismarsche Str. 43-45, Rostock 18051, Germany |
| |
| Abstract: | Grafting of styrene/maleic anhydride and methyl methacrylate/maleic anhydride binary monomers onto the low density polyethylene film was performed using the γ-ray irradiation technique. Then, the synthesized grafted films were treated with different ammonia derivatives for developing chelating functionalization. These chelating products were characterized by the gravimetric method as well as by the Fourier transformed infrared spectroscopic method, and were used for removal of arsenic and some heavy metals from aqueous solutions. The optimum absorbed dose of 30 kGy reveals the graft yielding of about 325% in the films. Uptake of arsenic and some heavy-metal ions (Cr(III), Mn(II), Fe(III), Ni(II), Cu(II) and Pb(II)) from contaminated water by the chelating functionalized films (CFF) was examined by an atomic absorption spectrophotometer. The maximum arsenic removal capacity of 5062 mg/kg has been observed for the film treated with hydroxylamine hydrochloride. The CFF prepared by semicarbazide and thiol analogs show affinity toward the metal ions with an order: Cu(II)>Fe(III)>Mn(II) etc. The results obtained from this study indicate that the functionalized films show good chelating and ion-exchange property for metal ions. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
