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Application of mass spectrometry to the study of fluoropolymers. III. Polyperfluorobut-2-yne
Authors:W. T. Flowers  R. N. Haszeldine  A. Janik  A. K. Lee  P. G. Marshall  R. D. Sedgwick
Abstract:Mass spectra of the volatile fractions from polyperfluorobut-2-yne have been obtained. The polymer appears to be thermally stable up to 300°C and molecules containing up to 12 monomer units have been identified. A regular structure is indicated by the mass spectrum which is characterized by unusually intense doubly charged ions. The endgroups are readily identified, and a conjugated polyolefin structure is indicated.
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