Reactions of a carbamoylstannane with acid chlorides: highly efficient synthesis of alpha-oxo amides |
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| Authors: | Hua Ruimao Takeda Hide-aki Abe Yoshimoto Tanaka Masato |
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| Affiliation: | Department of Chemistry, Tsinghua University, Beijing 100084, China. |
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| Abstract: | Treatment of acid chlorides with a carbamoylstannane under mild conditions (mostly rt for a few hours) affords alpha-oxo amides in high yields. Vicinal polycarbonyl compounds are also obtained, although spontaneous decarbonylation occasionally occurs. |
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