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Thermal decomposition of barium(II) tetraphenylborate |
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| Authors: | Zhou Bao-xue Zhong Wei-ke Zou Li-zhuang Wang Xiao-ling |
| Institution: | 1. Department of Chemistry, Shandong Normal University, 250014, Jinan 2. Shandong Provincial Environmental Monitoring Center, 250014, Jinan 3. Department of Chemistry, Shandong Yantai Teacher's College, 264025, Yantai, P. R. China |
| Abstract: | Barium(II) tetraphenylborate, Ba(Bph4))2·4H2O was prepared, and its decomposition mechanism was studied by means of TG and DTA. The products of thermal decomposition were examined by means of gas chromatography and chemical methods. A kinetic analysis of the first stage of thermal decomposition was made on the basis of TG and DTG curves and kinetic parameters were obtained from an analysis of the TG and DTG curves using integral and differential methods. The most probable kinetic function was suggested by comparison of kinetic parameters. A mathematical expression was derived for the kinetic compensation effect. |
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