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Calculation of 2p 4(3 P)nl(l=s,d) Rydberg spectra of the fluorine isoelectronic sequence
Authors:X. -Z. Qian  Z. -W. Wang
Affiliation:1. Department of Fundamental Science, Zhengzhou Institute of Electronic Technology, P.O. Box 1030, 450004, Zhengzhou, People's Republic of China
2. Institute of Atomic and Molecular Physics, Jilin University, 130023, Changchun, People's Republic of China
Abstract:The basic structure parameters of 2p 4(3 P)ns and 2p 4(3 P)nd (J=1/2, 3/2 and 5/2) Rydberg spectra for the fluorine isoelectronic sequence from FI to NiXX, as functions of effective nuclear charge, are calculated by using the eigenchannel quantum-defect theory. The results can be interpreted in terms of the variations of electrostatic and spin-orbit interactions along the sequence. A vast amount of basic atomic data can be obtained with these parameters as input. Some numerical examples are given, in which our results are in perfect agreement with experimental.
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