Synthesis and characterization of a polyoxovanadate cluster representing a new topology |
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| Authors: | Ishaque Khan M Ayesh Samar Doedens Robert J Yu Minghui O'Connor Charles J |
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| Affiliation: | Department of Biological, Chemical, and Physical Sciences, Illinois Institute of Technology, Chicago, IL 60616, USA. khan@iit.edu |
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| Abstract: | A new type of mixed-valence polyoxoanionic cluster, [V(V)13V(IV)3O42(Cl)]8-, composed of 14 {VO5} square pyramids and 2 {VO4} tetrahedral units, hosting a chloride ion has been synthesized and characterized. |
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