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Syntheses, structures, fluorescence and thermal properties of three lanthanide coordination polymers built by N-benzoyl-N′-(4-benzoxy)thiourea
Authors:Zi-Feng Li  Hui-Jie Lu  Hai-Fang Zhang
Institution:Department of Chemistry, Zhengzhou University, Henan 450052, P.R. China
Abstract:Three novel lanthanide 1-D chain coordination polymers, namely {Tb(μ2-L)2(η2-NO3)(CH3OH)(H2O)]·0.5CH3OH·0.5H2O}n (1), {Dy(μ2-L)2(η2-NO3)(CH3OH)(H2O)]·H2O}n (2) and {Ce(μ2-L)2(η2-NO3)(H2O)3]·H2O}n (3) (HL=N-benzoyl-N′-(4-benzoxy)thiourea), have been prepared and characterized by IR spectroscopy, elemental analysis and single-crystal X-ray diffraction. The luminescence properties and themostabilities of polymers 1-3 have been determined as well.
Keywords:Coordination polymer  Lanthanide  Crystal structure  Thermal properties  Fluorescence properties
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