Syntheses, structures, fluorescence and thermal properties of three lanthanide coordination polymers built by N-benzoyl-N′-(4-benzoxy)thiourea |
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Authors: | Zi-Feng Li Hui-Jie Lu Hai-Fang Zhang |
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Institution: | Department of Chemistry, Zhengzhou University, Henan 450052, P.R. China |
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Abstract: | Three novel lanthanide 1-D chain coordination polymers, namely {Tb(μ2-L)2(η2-NO3)(CH3OH)(H2O)]·0.5CH3OH·0.5H2O}n (1), {Dy(μ2-L)2(η2-NO3)(CH3OH)(H2O)]·H2O}n (2) and {Ce(μ2-L)2(η2-NO3)(H2O)3]·H2O}n (3) (HL=N-benzoyl-N′-(4-benzoxy)thiourea), have been prepared and characterized by IR spectroscopy, elemental analysis and single-crystal X-ray diffraction. The luminescence properties and themostabilities of polymers 1-3 have been determined as well. |
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Keywords: | Coordination polymer Lanthanide Crystal structure Thermal properties Fluorescence properties |
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