Synthesis and optical properties of N-In codoped ZnO nanobelts |
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Authors: | Lili Wu Zhengguo Gao Hong Gao XiTian Zhang |
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Affiliation: | a Heilongjiang Key Laboratory for Advanced Functional Materials and Excited State Processes, School of Physics and Electronic Engineering, Harbin Normal University, Harbin 150025, PR China b Center for Engineering Training and Basic Experimentation, Heilongjiang Institute of Science and Technology, Harbin 150027, PR China c Research Institute of Electronic Information Products Superintending and Inspecting, Heilongjiang Province, Harbin 15001, PR China |
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Abstract: | N-In codoped ZnO nanobelts were successfully synthesized via high-temperature chemical vapor deposition for the first time, using the mixture of In/ZnO as a precursor. The EDX spectrum showed that In was introduced into ZnO nanobelts. In order to better understand the optical properties of N-In codoped ZnO nanobelts, the Raman and low-temperature PL spectra of the undoped, In-doped and N-In codoped ZnO nanostructures were measured. By contrasting, N is incorporated into the nanobelts. The temperature dependent photoluminescence (PL) spectra were investigated. Their PL spectra in the temperature from 9 K to room temperature were dominated by an AoX emission of excitons bound to 2No-InZn acceptor complexes. The dissociation energy of the acceptor complexes is estimated to be 89-112 meV. |
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Keywords: | 78.67.Lt 78.30.Fs 81.07.Vb 81.15.Gh |
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