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Synthesis and optical properties of N-In codoped ZnO nanobelts
Authors:Lili Wu  Zhengguo Gao  Hong Gao  XiTian Zhang
Affiliation:a Heilongjiang Key Laboratory for Advanced Functional Materials and Excited State Processes, School of Physics and Electronic Engineering, Harbin Normal University, Harbin 150025, PR China
b Center for Engineering Training and Basic Experimentation, Heilongjiang Institute of Science and Technology, Harbin 150027, PR China
c Research Institute of Electronic Information Products Superintending and Inspecting, Heilongjiang Province, Harbin 15001, PR China
Abstract:N-In codoped ZnO nanobelts were successfully synthesized via high-temperature chemical vapor deposition for the first time, using the mixture of In/ZnO as a precursor. The EDX spectrum showed that In was introduced into ZnO nanobelts. In order to better understand the optical properties of N-In codoped ZnO nanobelts, the Raman and low-temperature PL spectra of the undoped, In-doped and N-In codoped ZnO nanostructures were measured. By contrasting, N is incorporated into the nanobelts. The temperature dependent photoluminescence (PL) spectra were investigated. Their PL spectra in the temperature from 9 K to room temperature were dominated by an AoX emission of excitons bound to 2No-InZn acceptor complexes. The dissociation energy of the acceptor complexes is estimated to be 89-112 meV.
Keywords:78.67.Lt   78.30.Fs   81.07.Vb   81.15.Gh
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