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Improved performances of red organic light-emitting devices by co-doping a rubrene derivative and DCJTB into tris-(8-hydroxyquinoline) aluminum host
Authors:Tianle Li  Wenlian Li  Xiao Li  Zisheng Su  Yiren Chen  Zhiqiang Zhang
Institution:a Physics Department, School of Science, Maoming University, Maoming 525000, People’s Republic of China
b Key Laboratory of Excited State Processes, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130033, People’s Republic of China
c Optic Photo-Electronic Materials and Research Development Center, Liaoning University of Science and Technology, Anshan 114044, People’s Republic of China
Abstract:Performances of red organic light-emitting device were improved by co-doping 2-formyl-5,6,11,12-tetraphenylnaphthacene (2FRb) and 4-(dicyanomethylene)-2-t-butyl-6-(1,1,7,7-tetra-methyljulolidyl-9-enyl)-4H-pyran (DCJTB) in tris-(8-hydroxyquinoline) aluminum (Alq3) host as the emitting layer. The device with 1 wt% DCJTB and 2.4 w% 2FRb in Alq3 host gave a saturated red emission with CIE chromaticity coordinates of (0.65, 0.35) and a maximum current efficiency as high as 6.45 cd/A, which are 2 and 2.4 fold larger than that of the device with 1 wt% DCJTB (3.28 cd/A) in Alq3 host and the device with 2.4 wt% 2FRb (2.72 cd/A) in Alq3 host at the current density of 20 mA/cm2, respectively. The improvement could be attributed to the effective utilization of host energy by both energy transfer and trapping in the electroluminescence process and the depression of concentration quenching between the dopants molecules.
Keywords:Co-doping  Red
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