| 一维链状铜配位聚合物[Cu(m-BDOA)(bipy)·H2O]n的合成与晶体结构 |
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| 引用本文： | 刘继伟,霍丽华,高 山,赵 辉,朱志彪,赵经贵. 一维链状铜配位聚合物[Cu(m-BDOA)(bipy)·H2O]n的合成与晶体结构[J]. 无机化学学报, 2004, 20(6): 707-710 |
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| 作者姓名： | 刘继伟 霍丽华 高 山 赵 辉 朱志彪 赵经贵 |
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| 作者单位： | 黑龙江大学化学化工学院,哈尔滨,150080 |
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| 基金项目： | 国家自然科学基金(No.20101003)，黑龙江省自然科学基金(No.B0007)，黑龙江省海外学人重点基金和校杰出青年基金 |
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| 摘 要： | A novel coordination polymer, [Cu(m-BDOA)(bipy)·H2O]n (m-BDOA2-=benzene-1,3-dioxyacetate), was synthesized and characterized by elemental analysis, IR spectra, X-ray single crystal structure analysis. Crystallographic data are as follows: orthorhombic, space group Pna21, a=1.606 9(3) nm, b=1.685 9(3) nm, c=0.699 7(1) nm, V=1.8955(7) nm3, Z=4, Dc=1.619 g·cm-3, μ=1.200 mm-1, F(000)=948，R=0.038 1, wR=0.038 6. The copper atom is five-coordinated involving two oxygen atoms of different m-BDOA2- ligand, two nitrogen atoms of 2,2′-bipy ligand and one coordinated water, there is a distorted square pyramidal environment. Two copper atoms are bridged by m-BDOA2- ligand, forming a one-dimensional chain along a axis. The adjacent distance of Cu…Cu atoms is 0.877 3nm. The crystal network was formed by the intermolecular hydrogen bond and π-packing interactions.
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| 关 键 词： | 配位聚合物 晶体结构 合成 |
| 修稿时间： | 2003-11-10 |
Synthesis and Crystal Structure of Coordination Polymer [Cu(m-BDOA)(bipy)· H2O]n with 1D Chain |
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| LIU Ji-Wei,HUO Li-Hu,GAO Shan,ZHAO Hui,ZHU Zhi-Biao and ZHAO Jing-Gui. Synthesis and Crystal Structure of Coordination Polymer [Cu(m-BDOA)(bipy)· H2O]n with 1D Chain[J]. Chinese Journal of Inorganic Chemistry, 2004, 20(6): 707-710 |
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| Authors: | LIU Ji-Wei HUO Li-Hu GAO Shan ZHAO Hui ZHU Zhi-Biao ZHAO Jing-Gui |
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| Affiliation: | College of Chemistry and Chemical Technology, Heilongjiang University, Harbin 150080,College of Chemistry and Chemical Technology, Heilongjiang University, Harbin 150080,College of Chemistry and Chemical Technology, Heilongjiang University, Harbin 150080,College of Chemistry and Chemical Technology, Heilongjiang University, Harbin 150080,College of Chemistry and Chemical Technology, Heilongjiang University, Harbin 150080 and College of Chemistry and Chemical Technology, Heilongjiang University, Harbin 150080 |
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| Abstract: | |
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| Keywords: | coordination polymer crystal structure synthesis |
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