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Stereochemie der heterocyclen—XXXI : Die konfiguration und bevorzugte konformation substituierter 4-methyl-1,3-dioxane
Authors:A.W. Bogatskij  Ju.Ju. Samitow  A.I. Gren  S.G. Sobolewa
Affiliation:Odessaer I. I. Metschnikow Staatsuniversität, Odessa, UdSSR Germany;Kasaner W. I. Uljanow-Lenin Staatsuniversität, Kasan, UdSSR Germany
Abstract:The configuration and conformation of some stereoisomers of 4,5-, 4,5,5- and 2,2,4,5-substituted 1,3-dioxanes are examined. The stereospecifity of the reduction of alkylacetoacetic esters to 2-alkylbutandiols-1,3 and to 4,5-, 2,2,4,5-substituted 1,3-dioxanes is studied. 1H-NMR-Data of cis- and trans-configurated 4,5- and 2,2,4,5-substituted 1,3-dioxanes are reported.
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