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Ionic hydrogenation of thiophenes
Authors:DN Kursanov  ZN Parnes  GI Bolestova  LI Belen&#x;kii
Institution:Institute of Organo-Element Compounds, Academy of Sciences, Moscow, USSR
Abstract:A new method of synthesising thiophane compounds by hydrogenation of the corresponding thiophenes with a mixture of triethylsilane and trifluoroacetic acid is described. A number of thiophanes, such as 2-, 3-alkyl-, arylthiophanes, 2,5-dimethylthiophane, thiophanes functionally substituted in the side chain and thiaindanes have been obtained by this method.
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