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A new displacement of CN- from saturated carbon |
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| Authors: | S Brenner M Bovete |
| Institution: | Department of Organic Chemistry, The Hebrew University, Jerusalem, Israel |
| Abstract: | Disubstituted nitriles, ketones and N-methylketimines can be synthesized by controlled reactions of nitriles, having an α activated methylene group, with methyllithium and methyliodide. Cyanide anion can be displaced from a tertiery carbon attached to naphthalene in a radical anion process. |
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