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Polycyanurate networks from anethole dimers: Synthesis and characterization
Authors:Matthew C Davis  Andrew J Guenthner  Thomas J Groshens  Josiah T Reams  Joseph M Mabry
Institution:1. Chemistry & Materials Division, Michelson Laboratory, Naval Air Warfare Center, China Lake, California 93555;2. Air Force Research Laboratory, Propulsion Directorate Edwards AFB, California 93524;3. National Research Council/Air Force Research Laboratory, Propulsion Directorate, Edwards AFB, California 93524
Abstract:Novel biorenewable bisphenols are obtained through simple and rapid chemical transformation of the natural product trans‐anethole. The corresponding dicyanate esters are thermally cured to give polycyanurate networks. The thermal properties from differential scanning calorimetry, thermogravimetric, and dynamic thermomechanical analyses of the new dicyanate esters compare favorably with similar commercial products. © 2012 Wiley Periodicals, Inc.? J Polym Sci Part A: Polym Chem, 2012
Keywords:anethole  curing of polymers  cyanate ester  high performance  high temperature materials  molding  polyphenol  renewable resources  synthesis  thermal properties  thermosets
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