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Struktur und stereochemie eines sesquiterpen-esters und dreier sesquiterpen-alkaloide von Celastrus paniculatus Willd
Authors:H Wagner  E Heckel  J Sonnenbichler
Institution:Institut für Pharmazeutische Arzneimittellehre der Universität München, MünchenFrance;Max-Planck-Institut für Biochemie, Martinsried bei München, MünchenFrance
Abstract:A new sesquiterpene ester (Malkangunin) and three sesquiterpene alkaloids (Celapanin, Celapanigin, Celapagin) were isolated from Celastrus paniculatus Willd. The complete structure and stereochemistry of Malkangunin, a sesquiterpene tetra-ol of the β-dihydroagarofurane type two of whose hydroxyls being esterified with acetic and benzoic acids, is discussed. The alkaloids described here are derived from a new sesquiterpene tetra-ol (Celapanol) which is alternately esterified with acetic, benzoic, nicotinic and β-furoic acids.
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