Synthesis and characterization of all‐conjugated copolymers of 3‐hexyl‐thiophene and EDOT by grignard metathesis polymerization |
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| Authors: | Luciano Miozzo Nicolas Battaglini Daniele Braga Loïg Kergoat Clément Suspène Abderrahim Yassar |
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| Affiliation: | Université Paris Diderot, Sorbonne Paris Cité, ITODYS, UMR 7086 CNRS, 15 rue Jean Antoine de Ba?f, 75205 Paris Cedex 13, France |
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| Abstract: | Random regioregular copolymers of 3‐hexylthiophene and 3,4‐ethylenedioxythiophene were synthesized by grignard metathesis polymerization. Soluble copolymers were obtained with a high degree of regioregularity and with a monomer ratio close to the feed ratio. A comparison between the optical properties and the thin film morphologies of these copolymers and poly(3‐hexylthiophene) is also presented. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 |
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| Keywords: | conducting polymers copolymerization conjugated polymers GRIM polymerization P3HT PEDOT |
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