Reactions of barium chloride dihydrate in potassium halide matrices: A differential scanning calorimetry study |
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Authors: | A.M. Wynne W.W. Wendlandt |
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Affiliation: | Department of Chemistry, University of Houston, Houston, Texas 77004 U.S.A. |
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Abstract: | The deaquation of BaCl2·2H2O in pressed KCl, KBr, and KI disks was followed by TG and DSC at pressures ranging from one to 34 atmospheres. Resolution of the DSC peaks of the first deaquation reaction and subsequent water vaporation was not improved by use of the matrix; for the second deaquation reaction, resolution was greater in the matrix. Evidence of a ternary eutectic involving BaCl2, KI, and H2O, which melted at 219°C, was obtained. |
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