Stereochemical studies of tricyclo[6.2.1.O.1·6]undecanes—II : Stereochemistry of isolongifolene epoxide |
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| Authors: | CW Greengrass R Ramage |
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| Institution: | The Robert Robinson Laboratories, University of Liverpool, Liverpool L69 3BX UK |
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| Abstract: | The stereochemistry of epoxidation and hydroboration of isolongifolene has been elucidated by comparison with the chemistry of the C2-desmethyl epoxides and their transformation products. The main factors controlling the stereochemistry of epoxidation of isolongifolene are the bicycloheptyl moiety and the C-2β methyl substituent. |
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