The reaction of α-chloro-α,α-diphenylacetamides with potassium n-cyanoanilide: A novel type of cine substitution |
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Authors: | Gy. Simig K. Lempert |
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Affiliation: | Research Group for Alkaloid Chemistry of the Hungarian Academy of Sciences, 1111-Budapest, Gellért tér 4, Hungary |
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Abstract: | Three types of products are formed in the reactions of α-chloro-α,α-diphenylacetamides (1a–c with potassium N-cyanoanilide: cine substitution products of type 2 as the main products, and two types of normal products (4a and b, and 3, 6 and 7a, respectively) whose formation reflects the ambident reactivity of the N-cyanoanilide anion. |
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