Investigation of Ultrafast Electronic Transfer Process on Organic/Inorganic Heterojunction by Femtosecond Transient Absorption |
| |
Authors: | Xue-cong Li Ning Sui Qing-hui Liu Qi-lin Yuan Ying-hui Wang |
| |
Affiliation: | 1.Department of Physics, Tianjin Polytechnic University, Tianjin 300387, China2.Femtosecond laser laboratory, College of Physics, Jilin University, Changchun 130012, China |
| |
Abstract: | We detect a relaxation process of excited SQ02 dye in the chlorobenzene solution and an-chor SQ02 on Al2O3 and TiO2 lm, so as to investigate the photophysical properties of pristine SQ02 in the monodisperse system, aggregation state, and the corresponding inter-facial electron transfer process. The experimental data show that the lifetime of SQ02 in the monondisperse system is ~2.0 ns, but that of SQ02 anchored on the Al2O3 lm could obviously decrease to ~21 ps. The time of electron transfer from excited SQ02 to TiO2 lm is estimated to be ~2.6 ps and the yield of electron injection is estimated to be ~89.1%, which matches the incident photon to current e ciency of dye-sensitized solar cell based on SQ02. In addition, some dyes are found to pack on the other dyes anchored on the nanocrystal lm, and their relaxation time could reach ~60 ps. They couldn't participate in the interfacial electron transfer, since they are far away from the TiO2 interface. |
| |
Keywords: | SQ02 dye Femtosecond transient absorption Photoexcitation dynamics |
|
| 点击此处可从《化学物理学报(中文版)》浏览原始摘要信息 |
|
点击此处可从《化学物理学报(中文版)》下载免费的PDF全文 |
|