CAN-mediated highly regio- and stereoselective oxidation of vinylidenecyclopropanes: a novel method for the synthesis of unsymmetrical divinyl ketone and functional enone derivatives |
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| Authors: | Su Chenliang Huang Xian Liu Qingyang |
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| Institution: | Department of Chemistry, Zhejiang University (Xixi Campus), Hangzhou 310028, People's Republic of China. |
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| Abstract: | CAN-mediated oxidative rearrangement of various vinylidenecyclopropanes under mild conditions generates unsymmetrical divinyl ketone and functional enone derivatives in moderate to good yields with excellent regio- and stereoselectivities. The reaction mechanism was investigated on the basis of an oxygen-18 tracer experiment. |
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